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I gave it one more try...
I thought I would go out and try one more...I realize now that this is way too hard a shot for my level of expertise (still fun to try though and play) and TI is probably right about the $$ involved. My dog is hardly trained to make perfect frisbee catches on command (but his recall is pretty good and he knows about 6 or so tricks).
Anyhow I used a flash this time to light him up and it is a cloudy day. I also played with exposure compensation. This is what I came up with... 1st shot is original...2nd shot is just a crop
Exif: Shutter priority 1/180 F8.0 200ISO
Flash used Exposure -.50
center weighted
WB cloudy setting